Product ID:L-605 HAYES 25, HIGH PERFORMANCE, HEAT RESISTANT ALLOYS
MSDS Date:03/01/1989
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CLNNY

ULBRICH STAINLESS STEELS & SPECIAL METALS

57 DODGE AVENUE
NORTH HAVEN, CT 06473
US

Emergency Phone: 203-239-4481

Info Phone: 203-239-4481

Preparer: ENVIRONMENTAL ENGINEERING

Cage: 0CU03

ULBRICH STAINLESS STEELS & SPECIAL METALS INC

NORTH HAVEN, CT 06473-1119 US

Telephone: 203-239-4481

Cage: 0CU03

CARBON

CAS: 7440-44-0

RTECS: FF5250000

Fraction By Weight: 0.05/0.15%

MANGANESE

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 1.0/2.0%

OSHA PEL C5 MG/M3

ACGIH TLV: 5 MG/M3

PHOSPHORUS

CAS: 7723-14-0

RTECS: TH3495000

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3;0.02 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SULFUR

CAS: 7704-34-9

RTECS: WS4250000

SILICON

CAS: 7440-21-3

RTECS: VW0400000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

CHROMIUM

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 19.0/21.0%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

NICKEL

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 9.0/11.0%

OSHA PEL 1 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

COBALT

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: BAL

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.02 MG/M3

IRON

CAS: 7439-89-6

RTECS: NO4565500

TUNGSTEN

CAS: 7440-33-7

RTECS: YO7175000

Fraction By Weight: 14.0/16.0%

ACGIH TLV: 5 MG/M3

Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:ACUTE-CAN CAUSE IRRITATION TO THE
SKIN, EYE & MUCOUS MEMBRANES. CONTACT WITH CHROME, COBALT, COPPER &
NICKEL MAY CAUSE ALLERGIC SKIN REACTIONS. EXCESSIVE INHALATION OF
ALUMINUM, COBALT, COPPER, MANGAN ESE, NICKEL & VANADIUM CAN CAUSE
RESPIRATORY IRRITATION, COUGH, BRONCHITIS, CHILLS, "FUME FEVER" &
ASTHMA0LIKE SYMPTOMS. CHRONIC-RESPIRATORY DISEASE WITH SYMPTOMS
RANGING FROM SHORTNESS OF BREATH & CO UGH TO PERMANENT DISABILITY
DUE TO LOSS OF LUNG FUNCTION, FIBROSIS OR SUBSEQUENT EFFECTS ON THE
HEART MAY BE CAUSED BY EXCESSIVE EXPOSURE TOD UST OR FUMES
CONTAINING COBALT, NICKEL, TITANIUM & TUNGSTE N. CNS DEPRESSION HAS
BEEN IDENTIFIED.
Explanation of Carcinogenicity:CHROME, NICKEL AND SOME OF THEIR
COMPOUNDS ARE LISTED BY NTP AND IARC AS CARCINOGENS.
Effects of Overexposure:INHALATION- INHALATION OF METAL DUST, FUME OR
POWDER MAY RESULT FROM MELTING, DROSS HANDLING, CASTING, WELDING,
GRINDING, CRUSHING OR SIMILAR OPERATIONS WHICH GENERATE AIRBORNE
METAL PARTICULATE DURIN G USE OF THIS MATERIAL. INGESTION-HAND,
CLOTHING, FOOD & DRINK CONTACT WITH METAL DUST/FUME/POWDER CAN
CAUSE INGESTION OF PARTICULATE DURING HAND TO MOUTH ACTIVITIES SUCH
AS EATING, DRINKING, SMOKING, NAIL BITING. SKIN-CONTACT WITH THIS
MATERIAL MAY CAUSE, IN SOME SENSITIVE INDIVIDUAL AN ALLERGIC
RESPONSE IF ELEMENTS SUCH AS CHROME, COBALT, COPPER, & NICKEL ARE
PRESENT, IN THE FORM OF METAL DUST/P OWDER;SKIN CONTACT MAY CAUSE
IRRITATION.
Medical Cond Aggravated by Exposure:INDIVIDUALS WHO MAY HAVE HAD
ALLERGIC REACTION OR SENITIVITY TO METALS MAY ENCOUNTER SKIN RASH
OR DERMATITIS IF SKIN CONTACT WITH THIS PRODUCT OCCURS.

First Aid:INHALATION-BREATHING DIFFICULTY REQUIRES REMOVAL TO FRESH
AIR. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION & GET
MEDICAL AID AT ONCE. INGESTION-CAN BE TREATED BY HAVING THE
AFFECTED PERSO N SWALLOW LARGE QUANTITIES OF WATER & ATTEMPTING TO
INDUCE VOMITING IF CONSCIOUS. OBTAIN MEDICAL AID AT ONCE. SKIN-CUTS
& ABRASIONS CAN BE TREATED BY STANDARD FIRST AID. CONTAMINATION CAN
BE REMOVED B Y WASHING WITH SOAP & WATER. FOR IRRITATION OBTAIN
MEDIAL AID. EYE-FLUSH FROM EYES WITH CLEAN WATER. FOR IRRIATION
OBTAIN MEDICAL AID. DO NOT WEAR CONTACT ELNSES WHEN USING
DUSTS/POWDERS.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:THIS ALLOY IS NONCOMBUSTIBLE. USE EXTINGUISHING
MEDIA APPROPIATE TO THE SURROUNDING FIRE.
Fire Fighting Procedures:IF THIS MATERIAL IS REDUCED TO POWDER FORM,
CAUTION MUST BE USED TO PREVENT FIRE OR EXPLOSION. TO EXTINGUISH A
METAL POWDER FIRE USE DRY SAND, DRY GRAPHITE OR OTHER CLASS "D"
FIRE EXTINGUISHING POWDER .
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE
ASSOCIATED WITH THIS MATERIAL.

Spill Release Procedures:INSOLID FORM THIS MATERIAL POSES NO SPECIAL
CLEAN-UP PROBLEMS. IF THIS MATERIAL IS IN POWDER/DUST FORM,
CLEAN-UP SHOULD BE DONE WITH A VACUUM SYSTEM UTILIZING A HIGH
EFFICIENCY PARTICULATE AIR FILTRAT ION SYSTEM. USE CAUTION TO
MINIMIZE AIRBORNE GENERATION OF POWDER/DUST & AVOID CONTAMINATION
OF AIR & WATER. PROPERLY LABEL ALL MATERIAL IN COLLECTED WASTE
CONTAINERS.

Handling and Storage Precautions:HANDLING-THIS PRODUCT MUST BE HANDLED
ACCORDINGLY TO THE SIZE, SHAPE & QUANTITY OF MATERIAL INVOLVED.
SOLID METAL MAY REQUIRE USE OF HOISTS, CRANES, ETC. POWDERS SHOULD
BE MOVED OR TRANSPORTED TO MINI MIZE SPILL OR RELEASE POTENTIAL.
Other Precautions:STORAGE-IN SOLID FORM THIS MATERIAL POSES NO SPECIAL
STORAGE PROBLEMS. STORE METAL & METAL POWDER IN A DRY AREA. DO NOTS
TORE ADJACENT TO MINERAL ACIDS. FINE METAL POWDER SHOULD BE KEPT
WAY FROM FLAME S & SOURCES OF IGNITION.

Respiratory Protection:USE NIOSH APPROVED RESPIRATORS AS SPECIFIED BY
AN INDUSTRIAL HYGIENIST OR QUALIFIED SAFETY PROFESSIONAL. LUNG
FUNCTION TESTS ARE RECOMMENDED FOR USERS OF NEGATIVE PRESSURE
DEVICES.
Ventilation:LOCAL EXHAUST VENTILATION SHOULD BE USED TO CONTROL
EXPOSURES TO AIRBORNE DUST & FUME WHENEVER POSSIBLE.
Protective Gloves:WEAR GLOVES TO PREVENT METAL CUTS & SKIN ABRASIONS.
Eye Protection:WEAR SAFETY GLASSES WHEN RISK OF EYE INJURY IS PRESENT.
Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS,
DISPOSABLE COVERALLS, SAFETY SHOES, ETC. MAY BE REQUIREDTAL
HANDLING OPEARTIONS AS APPROPIATE TO THE CIRCUMSTANCES OF EXPOSURE.
Work Hygienic Practices:AVOID BREATHING DUST OR FUME. IF THE USE OF
THIS MATERIAL PRODUCES DUST OR FUME, USE APPROPIATE VENTILATION
CONTROLS, PERSONAL PROTECTIVE EQUIPMENT OR BOTH.
Supplemental Safety and Health
MSDS IDENTIFICATION NUMBER: SA-006. TRADE NAME: HIGH PERFORMANCE, HEAT
RESISTANT ALLOYS. CHEMICAL FAMILY: ALLOY.

HCC:N1
Melt/Freeze Pt:=1329.4C, ######F
Vapor Density:NOT APPLIC
Spec Gravity:0.330
Solubility in Water:NONE
Appearance and Odor:SOLID-SILVER GRAY COLOR-NO ODOR.
Percent Volatiles by Volume:NONE

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH MINERAL ACIDS & OXIDIZING AGENTS WHICH MAY GENERATE
HYDROGEN GAS; THE EVOLUTION OF HYDROGEN MAY BE AN EXPLOSIVE HAZARD.
Stability Condition to Avoid:THIS ALLOY IS A STABLE MATERIAL.
Hazardous Decomposition Products:VARIOUS ELEMENTAL METALS & METAL
OXIDES MAY BE GENERATED FROM MELTING OR DROSS HANDLING OPERATIONS.

Waste Disposal Methods:PRIOR TO DISPOSAL CONSIDER IF THE MATERIAL HAS
RECOVERY VALUE. STATE OR FEDERAL REGULATIONS MAY REQUIRE SPECIFIC
LABELING, PACKING, STORAGE, TRANSPORTATION & DISPOSAL PROCEDURES.
CONTACT AN ENVIRONMEN TAL ENGINEER OR CONSULTANT FAMILIAR WITH
WASTE DISPOSAL REGULATIONS.

Toxicological Information:THERE IS NO INFORMATION ON THE TOXICITY OF
THIS ALLOY. UNDER NORMAL HANDLING & USE OF THE SOLID FORM OF THIS
MATERIAL THERE ARE A FEW HEALTH HAZARDS. CUTTING, WELDING,
GRINDING, ETC. OF THIS MATERIAL WILL PRODUCE DUST, FUME OR
PARTICULATE CONTAINING THE COMPONENT ELEMENTS OF THIS MATERIAL.
EXPOSURE TO THE DUST, FUME OR PARTICULATE MAY PRESENT SIGNIFICANT
HEALTH HAZARDS WHICH ARE REFERABLE TO THE ELEMENTAL CONSTITUENTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IN SOLID FORM THIS MATERIAL POSES NO SPECIAL ENVIRONMENTAL
PROBLEMS. METAL POWDERS OR DUSTS MAY HAVE SIGNIFICANT IMPACT ON AIR
& WATER QUALITY. AIRBORNE EMISSIONS, SPILLS & RELEASES TO THE
ENVIRONMENT (DISCHARGE TO STREAMS, SEWER SYSTEMS, GROUND WATER,
SURFACE SOIL, ETC.) SHOULD BE CONTROLLED IMMEDIATELY. IF SUCH
POTENTIAL FOR A SPILL EXISTS IT IS ADVISABLE TO DEVELOP AN
EMERGENCY SPILL RESPONSE P LAN.

Transport Information:SHIPPING NAME: NOT APPLICABLE. IDENTIFICATION
NUMBER: NOT APPLICABLE. HAZARD CLASS: NOT APPLICABLE. LABEL(S)
REQUIRED: NOT APPLICABLE.

SARA Title III Information:SOME OF THE PREVIOUSLY LISTED CHEMICALS ARE
SUBJECT TO ANNUAL REPORTING OF RELEASES INTO THE ENVIRONMENT UNDER
SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY
RIGHT-TO-KNOW-ACT OF 1986. IT IS THE RESPONSIBILITY OF THE USER TO
VERIFY WHETHER OR NOT HIS OR HER FACILITY IS IN COMPLIANCE WITH ALL
FEDERAL AND STATE ENVIRONMENTAL REGULATIONS.
State Regulatory Information:NOTICE: CALIFORNIA LISR. OUR MATERIAL
SAFETY DATA SHEET HAVE BEEN REVIEWED FOR INCLUSION OF ANY CHEMICALS
LISTED UNDER THE SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF
1986 (CALIFORNIA PROPOSITION 65). WE AT THIS TIME DO NOT REPORT
ANY OF THE "LISTED" CHEMICALS AS CONSTITUENT COMPONENTS IN ANY
ALLOYS CURRENTLY PROCESSED BY OUR COMPANY.